To merge columns, use \multicolumn{no. of cols}{formatting}
{text}:
\documentclass[a4paper,12pt]{article}
\usepackage{booktabs}
\begin{document}
\section*{Tables: merging columns}
\begin{table}
\centering
\begin{tabular}{lll}
\toprule
Header: column 1 & \multicolumn{2}{c}{Header: columns 2--3} \\
& Subheader: column 2 & Subheader: column 3 \\
\midrule
Row 1, column 1 & Row 1, column 2 & Row 1, column 3 \\
Row 2, column 1 & Row 2, column 2 & Row 2, column 3 \\
\bottomrule
\end{tabular}
\end{table}
\end{document}
The formatting is of the type you’d use with a tabular
environment and the number of columns is how many columns you want to merge.
The booktabs package was used to produce pretty horizontal lines.